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高分子物理基础（Fundamental of Polymer Physics） 
定 价：98 元
9 7 4 8 4 7 7 5 6 1 4 8 0 
《高分子物理基础（Fundamental of Polymer Physics）》为全英文教材，通过研究聚合物的分子运动，揭示了结构与性能之间的内在联系和基本规律，为聚合物的合成、设计、制备与改性、成型、性能测试和质量控制提供理论依据。本教材系统地介绍了高分子物理的
基本概念和理论，并介绍了相关的实际应用案例和各部分的最新进展。本书共分为11章，包括5个部分：①绪论；②高聚物的结构，包括分子量和分布、链结构、聚集态结构、溶液和共混结构；③高聚物的分子运动；④高聚物的性能，包括力学性能和电学性能；⑤聚合物 的典型测试和表征方法。
卞军，西华大学材料科学与工程学院教授，研究方向为高分子材料，参与国家级项目和主持省部级及其以上项目7项，主持市厅级项目、校级科研项目10余项以及多项企业委托项目。是材料科学与工程四川省特色专业建设项目和卓越工程师项目建设的主研人员（排名第2
），是“材料专业综合改革项目”校级教学团队建设项目负责人。 蔺海兰，2006年毕业于海南大学高分子材料专业，工学硕士。2011年4月调到西华大学材料科学与工程学院工作，工程师、助理研究员。
Contents
Contents高分子物理基础Chapter 1Introduction1 11The importance of polymer science and engineering1 12The task of polymer physics1 121The main task of polymer physics1 122Main contents and the requirements of the course2 13The definition and the chemical nature of polymers2 131Introduction2 132The classification of polymers4 133Classical polymerization processes7 134Newer polymers and polymerization processes11 14A brief history of the development of polymer science and synthetic polymers12 141Development of polymer science12 142Development of synthetic polymers16 15Properties and applications of polymers20 16Polymer processing22 161Introduction22 162Additives and composites22 163Polymer processing23 Questions25 Reference25 Chapter 2Molecular sizes—the molecular mass and distribution27 21Introduction27 22Statistical significance of polymer molecular mass28 23Characterization methods of polymer molecular mass28 24Characterization method of the molecular mass distribution30 25Determination of molar masses and distributions33 251Endgroup Analysis35 252Osmotic Pressure 36 253Light Scattering 38 254Flight Time 46 255Viscometry 51 26Determination Methods of Molecular Mass Distribution54 261Phase Separation and Fractionation 54 262Gel Permeation Chromatography 55 Questions59 Reference61 Chapter 3The chain structure of polymers65 31Introduction65 32Construction66 33Configuration68 331Bonding methods of monomer68 332Branching70 333Crosslinking 71 334Sequential structure of copolymer 72 335Configuration isomerism of polymer chains 74 34Conformation77 341Size and shape of polymer chain78 342The shapes of polymer molecules79 343The internal rotational conformation and flexibility of a polymer chain83 344The single freely jointed chain90 345More realistic chainsthe excluded volume effect92 346Characteristics of polymer chain flexibility94 347Wormlike chains95 Questions96 Reference97 Chapter 4The condensed structure of polymers98 41Introduction98 42Forces between polymer molecules99 421Van der Waals force and hydrogen bond99 422Cohesive energy and cohesive energy density101 43The structure model of amorphous polymer102 431Three structural models of amorphous state102 432The macroconformations of polymers103 433Lamellar stacks104 44Crystalline state of polymers105 441Crystal morphology of crystalline polymers 105 442Crystallization process of polymer117 443Structural model of crystalline polymers126 45Crystallinity129 451Definition of crystallinity129 452Experimental determination of crystallinity130 453Factors influencing crystallinity133 454The effect of crystallinity on polymer properties138 46Melting and melting point of crystalline polymers142 461Melting thermodynamic analysis of crystalline polymers142 462Melting characteristics of crystalline polymers142 463Influencing factors of polymer melting point144 47Orientation state of polymer153 471Orientation phenomenon of polymer153 472Orientation mechanism155 473Degree of orientation and its testing methods156 474Applications of orientation156 48Liquid crystal state of polymer159 481The structure of polymer liquid crystal159 482Characteristics of polymer liquid crystals161 483Application of polymer liquid crystal163 Questions164 Reference165 Chapter 5Polymer solution167 51Introduction167 52Polymer dissolution process and solvent selection168 521Characteristics of polymer dissolution processes170 522Thermodynamic explanation of polymer dissolution process172 523Selection of polymer solvent176 53FloryHuggins polymer solution theory178 531Mixing entropy（ΔSm)179 532Heat of mixing181 533Chemical potential of polymer solution183 54Ideal solution of polymer184 55Nonideal behavior theory of polymer solutions186 551FloryKrigbaum dilute solution theory186 552FloryRehner solution theory189 553Van′t Hoff dilution theories190 56Phase equilibrium and phase separation of polymer solutions191 57Scaling concept and scaling law of polymers194 58Semidilute polymer solutions195 581The dilute to semidilute transition196 582The size of a polymer chain in a semidilute solution197 583A series drop model of semidilute solution197 584Osmotic pressure of a semidilute solution198 59The influence of temperature and concentration on the size of polymeric chains in a solution200 510Polymer gels200 511Polyelectrolyte solution201 512Diffusion of polymers in solution203 513Viscous motion of flexible polymers in dilute solution205 Questions210 Reference211 Chapter 6Polymer blends212 61Introduction212 611Polymer blends and its category212 612Types of polymer blends and expression of blends composition212 613Advantages of polymer blending 213 62Preparation methods of polymer blends215 63Thermodynamic basis of polymer blends216 64Compatibility and compatibilization of polymer blends218 641Fundamental concept of polymer compatibility218 642Compatibility prediction219 643Research methods of compatibility220 644Methods to enhance compatibility224 65Morphology of polymer blends225 651Types of morphology in polymer blends225 652Factors influencing the phase morphology of polymer blends231 66Phase interfaces of blends234 661Factors related to polymer surface tension234 662Interfacial tension of polymerpolymer twophase system236 663Interface layer and interface action237 67Performance of polymer blend systems240 671Factors affecting blend performance241 672General relationship between the properties of polymer blends and their components242 673Mechanical properties of polymer blends248 674Rheological properties of polymer blends248 675Glass transition of polymer blend systems251 Questions255 Reference256 Chapter 7Motion of polymer molecules257 71Introduction257 72Characteristics of thermal motion of polymer molecules257 73Polymer molecular motion and mechanical state260 731Mechanical state transition of amorphous polymers260 732Secondary relaxation transition263 74The glass transition of polymers263 741Evidence of the glass transition in polymers263 742The theory of glass transition in polymers265 743Measurement of Tg269 744Factors affecting the Tg273 75Viscous flow284 751The movement of chains during polymer viscosity flow284 752The snakelike motion of polymer chains and the pipe model in viscoelastic flow285 753Factors of influence on viscosity flow temperature287 754Factors affecting the viscosity of polymer melt292 Questions297 Reference299 Chapter 8Mechanical properties of polymersPart I：Tensile，Yield， Break and Strength300 81Introduction300 82Basic physical quantities and mechanical performance parameters301 83Tensile behavior of polymers309 831Stressstrain curves of glassy state polymers313 832The stressstrain curve of crystalline and semicrystalline polymers316 833Tensile behavior of hardelastic polymers 317 834Plasticrubber transition by strain319 84Yield of polymers321 85Fracture theory and theoretical strength of polymers322 851Fracture theory322 852Theoretical strength of polymers327 86Factors that influence the actual strength of polymers329 861Effects of structural factors of polymers329 862Effects of crystallization and orientation330 863Effects of stress concentration331 864Effects of plasticizers333 865Effects of fillers333 866Effects of copolymerization and blending337 867The influence of external force acting speed and temperature338 Questions339 Reference341 Chapter 9Mechanical properties of polymersPart Ⅱ：High elasticity and viscoelasticity342 91Introduction342 92Physical properties of hyperelastic polymers343 921The phenomenology of rubber elasticity343 922Characteristics of hyperelasticity349 923The thermodynamic analysis of rubber elasticity354 924The statistical theory of rubber elasticity355 93Swelling of crosslinked networks and the ultimate properties of rubber365 94Mechanical relaxation of polymersviscoelasticity366 941Mechanical relaxation phenomenon of polymers366 942Mechanical models of viscoelasticity369 95The relationship between viscoelasticity and time，temperaturetime equivalence principle374 96Boltzmann superposition principle376 97Experimental methods for studying viscoelastic behaviour378 971Transient measurements378 972Dynamic measurementsthe complex modulus and compliance379 973Dynamic measurements；examples380 98Relaxation transformation and molecular mechanism of polymers387 Questions394 Reference397 Chapter 10Other properties of polymers398 101Introduction398 102Electrical properties of polymers398 1021Dielectric properties of polymers398 1022Polymer conductivity409 1023Electrostatic phenomena in polymers410 1024Other electrical properties of polymers411 103Optical properties of polymers412 104Permeability of polymers413 1041Definition413 1042Gas permeation theory413 1043Major factors affecting gas permeability414 105Surface and interface properties of polymers415 1051The bonding properties of the interface416 1052Performance of Polymer Adhesives417 1053Surface modification417 106Thermal Performance418 1061Thermal resistance performance418 1062Thermal decomposition of polymers422 1063Thermal conductivity of polymer425 1064Thermal expansion property425 1065Specific heat（heat capacity)427 107Biocompatibility of polymer materials427 1071Special requirements for bone cement427 1072Polymeric materials for blood contact428 Questions429 Reference429 Chapter 11Analyzing and characterizing methods of polymers432 111Introduction432 112Infrared and Raman spectroscopy432 1121Infrared Spectroscopy 432 1122Laser Raman spectroscopy 435 113Mass spectrometry437 1131The basic principle of mass spectrometry 437 1132The application of mass spectrometry438 114Nuclear magnetic resonance method439 1141Chemical shift440 1142Fourier transform nuclear magnetic technology 442 1143Spinspin coupling，dipole decoupling and cross polarization442 1144Magic Angle Spinning443 1145Application of NMR in the study of polymer chain structure444 1146Nuclear magnetic resonance microscopic imaging technology 445 115Smallangle laser scattering method446 1151The principle of measuring spherulite size by small angle laser scattering method 446 1152Study on phase separation process by small angle laser scattering method448 116Dynamic light scattering method449 1161Data processing of dynamic light scattering 452 1162Application of dynamic light scattering 453 117Xray diffraction and small angle Xray scattering454 1171Xray diffraction study of crystal structure 454 1172Xray small angle scattering method 457 118Small angle neutron scattering method460 119Laser confocal microscope463 1110Electron microscope464 11101The construction principle of transmission electron microscope 464 11102Experimental method of transmission electron microscope 465 11103The application of transmission electron microscopy 467 11104Scanning electron microscope468 1111Atomic force microscope（AFM)471 11111The working principle and device composition of AFM471 11112Working mode of AFM 473 11113Application of AFM475 1112Thermal analysis of polymersDSC and DTA476 1113Thermal stability analysis of polymer479 Questions480 Reference481
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